For insulator
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•
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The forbidden energy gap is very large (fig c). It is more than 3 eV and almost no
electrons are available for conduction
Therefore, a very large amount of energy must be supplied to a valence
electron to enable it to move to the conduction band
If the electron is supplied with high energy, it can jump across the forbidden
gap. When the temperature is increased, some electrons will move to the
conduction band. This is the reason, why certain materials, which are
insulators at room temperature become conductors at high temperature
Difference between conductor, insulator and semiconductor
Conductor
Insulator
Semiconductor
The conductivity of
conductor is very high.
It has very low resistivity.
The conductivity of
insulator is very low.
It has very high resistivity.
The conductivity of
semiconductor is moderate.
It has moderate resistivity.
It has no forbidden gap.
It has large forbidden gap.
It has small forbidden gap.
Has positive temperature
coefficient of resistance.
Has negative temperature
coefficient of resistance.
Has negative temperature
coefficient of resistance
Both the effect of resistance
and temperature are
increasing
The effect of resistance
decreases with the increase
of temperature
The effect of resistance
decreases with the of
temperature increases.
There is large number of
electrons available for
conduction.
There is small number of
electrons available for
conduction.
There is moderate number of
electrons available for
conduction.
Examples
:
are Metals
Paper, Wood, Mica glass.
Silicon, Germanium.
(aluminium, copper.etc)
How Semiconductor Conducts Electricity
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As the temperature is increased, some of the electrons in the valence band
acquire thermal energy that is greater than the forbidden gap energy and move
to the conduction band. Therefore, the material becomes a conductor. When
an electron moves out of a valence band it leaves behind a small space called
a
hole. Electrons and holes in the conduction and valence bands, respectively,
are referred to as free charge carriers
.
Effect of temperature on metal conductivity
•
Increase in temperature tends to increase the random motion of electrons. It
reduces the electrical conductivity of metals
Types of Semiconductors
o
o
Intrinsic semiconductors
Extrinsic semiconductors